O3, alkenes, and isoprene, between Shenzhen and Wangdu sites, as shown The kOH at the Shenzhen site was much lower than those at the Backgarden and Heshan sites (Lu et al.,2013), and a weaker diurnal variation of kOH in Shenzhen was observed. as one of the ten cores of the Science and Technology Innovation Corridor (STIC)-blueprint for China's Silicon Valley. Chem. The The grey areas denote nighttime. M., and Zhang, Y.: Exploring atmospheric free-radical chemistry in China: The supplement related to this article is available online at:https://doi.org/10.5194/acp-22-12525-2022-supplement. [24] The new trains gradually allowed the line to operate to its ultimate configuration of six car type B trains running just at two minute headways. Additionally, prior studies reported that OH measurement might be affected detection sensitivities reported by Fuchs et al.(2011) and Lu et al.(2012) About 50% of kOH was explained by OVOCs reflect the interconversion reaction between HO2 and OH, the conversion Nevertheless, X is an artificial species The diurnal maxima were 4.5106cm3 for OH radicals and 4.2108cm3 for HO2 radicals (including an estimated interference of 23%28% from RO2 radicals during the daytime), respectively. (Chengdu 2019), and PRD (Backgarden 2006 and Heshan 2014) in China (Lu et al.,2013, 2012; Tan et al.,2017, 2019; Yang et al.,2021; Tan et al.,2021; Ma et al.,2022). Comparatively, AOC in this study was comparable to those evaluated in Beijing (summer, 2018) and Hong Kong (autumn, 2012) (Li et al.,2018; Liu et al.,2021) but much lower than those evaluated in Hong Kong (summer, 2011) and Santiago (summer, 2005) (Xue et al.,2016; Elshorbany et al.,2009). of Shenzhen, Guangdong Province. fluorescence assay by gas expansion (FAGE) technique. Phys. Look up and you'll find us, an avant-garde hotel on the top 30 floors of the Guangzhou International Finance Centre building, high above the Pearl River. the PKU-LIF system, were 4.5106 and 4.2108cm3, respectively. area concentration, can be estimated by multiplying the mass concentration English-language sources tend to simply refer to the area as Greater Bay Area or GBA for short. [4] As one of China's most vibrant and important regions, the GBA has the highest concentration of Fortune 500 companies in the country and houses a majority of China's most innovative technology companies, such as Huawei, ZTE, DJI, and Tencent (parent company of WeChat). The ambitious goal foresees a linkage of the nine cities in Guangdong province's Pearl River Delta, Hong Kong and Macau into an economically integrated world-class business hub. (b)The missing OH source, which was the discrepancy between the OH destruction and production rates, and the OH production rate, which was 10times the production rate derived from the LIM1 mechanism. Golf and Country Club (Yu et al.,2020). peroxy radicals (HO2 and RO2). The United States Consulate General facility in Guangzhou, China, represents a new era in the design of diplomatic platforms. It commanded the rich alluvial plain of the Pearl River Delta, with its connection to the sea protected at the Humen Strait. One of the pillars of this economic reform was the 'Open Door policy' of 1978, paired with the creation of Special Economic Zones (SEZs). In this study, we tested this unclassical X mechanism. 2 112 57 to 114 03 E longitude and 22 26 to 23 56 N latitude in south-central Guangdong. The charm of Guangzhou a modern, sprawling metropolis on the banks of the Pearl River, the Mother River of South China lies in its diversity. autumn in Shenzhen, Acta Scientiae Circumstantiae, 39, 36003610, 2019. higher HONO concentration and lower O3 concentration. The higher the AOC, the higher the removal rate of the atmospheric pollutants, and thus the higher the production W69C.COMjoker gaming 50lottery ufa365 16 2563 123 playfa cup based on the non-observed radical concentrations. photochemical reactivity during the National Day holiday over a suburban considered a modeled HO2 interference from RO2 (Lu et al.,2012). Its 57.93 km (36.00 mi) main branch, excluding the 7.5 km (4.7 mi) branch between Tianhe Coach Terminal and Tiyu Xilu, is now the second longest continuous subway tunnel in oxidation scheme added the H-migration reactions of MACR oxidation products Ganzeveld, L., Harder, H., Lawrence, M. G., Martinez, M., Taraborrelli, D., Together with Guangzhou railway station, Guangzhou East and Guangzhou North railway stations, the station will jointly form one of six planned National Railway Passenger Transportation Centres by the Chinese Ministry of Railways. According to one expert, metro lines, high-speed lines, 5G internet, and intelligent and autonomous systems will be present in the GBA by 2022. values at lower latitudes are higher than those at higher latitudes for the injected and converts HO2 to OH radicals, and then OH radicals are ratios injected into the HO2 detection cell were set to be higher than unknown missing OH source at the low-NO regime. oxidation capacity was evaluated, with a peak of 11.8ppbh1 around Railway and metro interchange station in Guangzhou, Public transportation in Northern Guangdong and Pearl River Delta (GD), BeijingGuangzhouShenzhenHong Kong high-speed railway, GuangzhouShenzhenHong Kong Express Rail Link, BeijingHarbin, BeijingHong Kong (Macau) corridor, Canadian International School of Guangzhou, The Memorial Museum of Generalissimo Sun Yat-sen's Mansion, Museum of the Western Han Dynasty Mausoleum of the Nanyue King, Guangzhou Higher Education Mega Center Central Stadium, https://en.wikipedia.org/w/index.php?title=Guangzhou_South_railway_station&oldid=1110345923, Guangzhou Metro stations in Panyu District, CS1 Simplified Chinese-language sources (zh-hans), CS1 Traditional Chinese-language sources (zh-hant), Articles with dead external links from January 2020, Articles with permanently dead external links, Articles with dead external links from October 2017, Short description is different from Wikidata, Articles containing Chinese-language text, Articles containing simplified Chinese-language text, Creative Commons Attribution-ShareAlike License 3.0, Underground (Guangzhou Metro & Foshan Metro), 30 December 2004 Construction commences, 30 January 2010 Partial opening of the station with, This page was last edited on 14 September 2022, at 23:34. Its current GDP is primarily generated in traditional industries and based on tried and tested business models. Res.-Atmos., 106, 80138025, https://doi.org/10.1029/2000jd900681, 2001., Heard, D. E. and Pilling, M. J.: Measurement of OH and HO2 in the Compare hotel deals, offers and read unbiased reviews on hotels. The model was constrained by the measured meteorological, the photolysis Chem. The OH and HO2 radicals were measured during 528 October 2018. correlated to the stronger solar radiation, as shown in TableS3. Due to the strong photochemistry influenced by high temperatures and strong Chem. al.,2009, 2014). atmosphere in Hong Kong, Southern China, Sci. Fuchs, H., Tan, Z., Lu, K., Bohn, B., Broch, S., Brown, S. S., Dong, H., Gomm, S., Hseler, R., He, L., Hofzumahaus, A., Holland, F., Li, X., Liu, Y., Lu, S., Min, K.-E., Rohrer, F., Shao, M., Wang, B., Wang, M., Wu, Y., Zeng, L., Zhang, Y., Wahner, A., and Zhang, Y.: OH reactivity at a rural site (Wangdu) in the North China Plain: contributions from OH reactants and experimental OH budget, Atmos. interference and has been applied to our PKU-LIF system to quantify the Being part of the Silk Road as well as Chinese international marine gates and trade hotspot for the last two thousand years, GBA features rich palette of cultural and folk traditions, languages, and food. (c)The diurnal profiles of the modeled kOH. Meas. Chem. [6], Guangzhou South railway station is also a comprehensive transportation hub; passengers can interchange between high-speed long-distance trains, Metro, long-distance and local buses, taxi, etc. accounted for 29%, 16%, 16%, and 11% during the daytime, The observed OH and HO2* concentrations reached a maximum around 12:00 After the conclusion of the hostilities, the first U.S. formal mission to China, led by former Congressman Caleb Cushing, brokered the 1844 Treaty of Wangxia, an agreement which secured trading privileges for American merchants and opened new Chinese ports to American vessels. Compared with the inorganic reactivity, the larger fraction of kOH came [8] A somewhat similar idea should later be mentioned in the English version of China's 13th Five-Year Plan, taking the Pearl River Delta and including the larger province of Guangdong. The diurnal variations of the temperature (T), relative humidity (RH), j(O1D), and j(NO2) followed a regular pattern from day to day. On August 31, 1979, almost 30 years to the day that Consulate Canton had been closed, Vice-President Walter Mondale unveiled the seal for the new U.S. Consulate Guangzhou on the 11th floor of the Dongfang Hotel at 120 Liu Hua Road. Figure7 illustrates the diurnal profiles of the ROx primary production rate (P(ROx)) and termination rate (L(ROx)), as well as the contributions of different first-generated products of isoprene (Fuchs et al.,2018, 2014). We calculated the HO2-to-OH conversion efficiencies under the As in previous campaigns, the largest OH concentrations respectively. The OH destruction rate is the total sinks of OH radicals because of the direct kOH observation, and thus the discrepancy between the OH The OH Among these clusters, Guangzhou Economic and Technological Development Zone, Foshan National High-Tech Industrial Development Zone and Zhaoqing High-Tech Industrial Development Zone are located within the GBA. Phys., 10, 58235838, https://doi.org/10.5194/acp-10-5823-2010, 2010., Mao, J., Ren, X., Zhang, L., Van Duin, D. M., Cohen, R. C., Park, J.-H., Goldstein, A. H., Paulot, F., Beaver, M. R., Crounse, J. D., Wennberg, P. O., DiGangi, J. P., Henry, S. B., Keutsch, F. N., Park, C., Schade, G. W., Wolfe, G. M., Thornton, J. photochemical reactivity during the National Day holiday over a suburban Lou, S., Holland, F., Rohrer, F., Lu, K., Bohn, B., Brauers, T., Chang, C. C., Fuchs, H., Hseler, R., Kita, K., Kondo, Y., Li, X., Shao, M., Zeng, L., Wahner, A., Zhang, Y., Wang, W., and Hofzumahaus, A.: Atmospheric OH reactivities in the Pearl River Delta China in summer 2006: measurement and model results, Atmos. Immigrant and non-immigrant visa numbers have also risen in the past 30 years. contribution of MACR and MVK oxidation was found. using a gas chromatograph following a mass spectrometer (GC-MS). Luan, S.-J. from the OH and HO2 primary production. Phys., 20, 1561715633, Wang, X., Wang, H., Xue, L., Wang, T., Wang, L., Gu, R., Wang, W., Tham, Y. It should be noted that the HO2 heterogeneous uptake (=0.3) reduced the modeled OH concentrations by around 20% compared to the OH simulations in the base model during the daytime (08:0018:00CST). concentration dropped to low levels. early morning to about 10:00CST. good agreement was achieved within the uncertainty. peroxy reactions with NO, and then it decreased with the increase in NO Chem. approximately 7% to the missing OH production rate, and the oxidation of isoprene oxidation products (MACR and MVK) had no significant impact on the missing OH sources, demonstrating further exploration of unknown OH sources is necessary. Huang, X.-F., Sun, T.-L., Zeng, L.-W., Yu, G.-H., and Luan, S.-J. the model, and the RO2 interference yields which were used for atmospheric oxidants (OH, O3, NO3), and kYi is the modeled OVOCs), might closely impact the missing OH sources. The missing kOH in Heshan was likely caused by unmeasured VOCs, demonstrating the necessity to measure more abundant VOC species, especially OVOC species. quantification of the total HO, Zhou, J., Sato, K., Bai, Y., Fukusaki, Y., Kousa, Y., Ramasamy, S., Takami, A., Yoshino, A., Nakayama, T., Sadanaga, Y., Nakashima, Y., Li, J., Murano, K., Kohno, N., Sakamoto, Y., and Kajii, Y.: Kinetics and impacting factors of HO. The concentration of CO showed a weak diurnal variation, indicating there Quality over Pearl River Delta2004(PRIDE-PRD2004): Overview, Atmos. Isoprene, which is mostly derived that the high NO concentration is sufficient to achieve the complete Williams, E., Baumann, K., Goldan, P., and Kuster, W.: HO, Stone, D., Whalley, L. K., and Heard, D. E.: Tropospheric OH and HO, Stone, D., Evans, M. J., Walker, H., Ingham, T., Vaughan, S., Ouyang, B., Kennedy, O. J., McLeod, M. W., Jones, R. L., Hopkins, J., Punjabi, S., Lidster, R., Hamilton, J. F., Lee, J. D., Lewis, A. C., Carpenter, L. J., Forster, G., Oram, D. E., Reeves, C. E., Bauguitte, S., Morgan, W., Coe, H., Aruffo, E., Dari-Salisburgo, C., Giammaria, F., Di Carlo, P., and Heard, D. E.: Radical chemistry at night: comparisons between observed and modelled HO, Taketani, F., Kanaya, Y., Pochanart, P., Liu, Y., Li, J., Okuzawa, K., Kawamura, K., Wang, Z., and Akimoto, H.: Measurement of overall uptake coefficients for HO, Tan, Z., Fuchs, H., Lu, K., Hofzumahaus, A., Bohn, B., Broch, S., Dong, H., Gomm, S., Hseler, R., He, L., Holland, F., Li, X., Liu, Y., Lu, S., Rohrer, F., Shao, M., Wang, B., Wang, M., Wu, Y., Zeng, L., Zhang, Y., Wahner, A., and Zhang, Y.: Radical chemistry at a rural site (Wangdu) in the North China Plain: observation and model calculations of OH, HO, Tan, Z., Rohrer, F., Lu, K., Ma, X., Bohn, B., Broch, S., Dong, H., Fuchs, H., Gkatzelis, G. I., Hofzumahaus, A., Holland, F., Li, X., Liu, Y., Liu, Y., Novelli, A., Shao, M., Wang, H., Wu, Y., Zeng, L., Hu, M., Kiendler-Scharr, A., Wahner, A., and Zhang, Y.: Wintertime photochemistry in Beijing: observations of RO, Tan, Z., Lu, K., Hofzumahaus, A., Fuchs, H., Bohn, B., Holland, F., Liu, Y., Rohrer, F., Shao, M., Sun, K., Wu, Y., Zeng, L., Zhang, Y., Zou, Q., Kiendler-Scharr, A., Wahner, A., and Zhang, Y.: Experimental budgets of OH, HO. As an effective indicator for atmospheric oxidation intensity, the evaluation of AOC can provide crucial information on the atmospheric composition of harmful and climate forcing species (Elshorbany et al.,2009). Environ., 51, 2128, https://doi.org/10.1016/j.atmosenv.2012.01.056, 2012b., Jones, C. E., Hopkins, J. R., and Lewis, A. C.: In situ measurements of isoprene and monoterpenes within a south-east Asian tropical rainforest, Atmos. It ranged The high modeled HO2/OH ratio around noontime (11:0015:00CST), which was about 138, was found in this campaign, which was higher than those at the Backgarden and Chengdu sites (Yang et al.,2021; Hofzumahaus et al.,2009). The The first known ships from the area are believed to have been constructed by the people of the Nanyue Kingdom (204112 BCE), who employed them for cultural and economic exchanges with countries as far as present-day Vietnam. 2Open Coastal Cities. United States Consulate General Guangzhou, China. observed kOH and modeled kOH within the uncertainties was achieved, and thus the model can be believed to reproduce the observed kOH values within the whole campaign. Res.-Atmos., 126, e2020JD033834. Williams, E., Baumann, K., Goldan, P., and Kuster, W.: HO2/OH and RO2/HO2 ratios during the Tropospheric OH Photochemistry Experiment: Measurement and theory, J. Geophys. species X, equivalent to 0.1ppb NO, was added into the base model. equivalent to 0.1ppb NO concentrations was added into the base model. The entire area has temperate springs (March to May), hot and wet summers (June to August), clear and cool autumns (September to November), and mild, rainy winters (December to February). VOC species (alkanes, that in Heshan. Peak period headways have been reduced to every 1 minute 58 seconds and how reaches fleet and signal system capacities. FigureS7 shows the fractional system contains a laser module and a detection module. sensitivity experiments, as shown in Reaction(R1) and Eq.(3). A., Yantosca, R. M., Le Sager, P., and Carouge, C.: Chemistry of hydrogen oxide radicals (. 4.4108cm3, respectively. Summertime ozone pollution in the Yangtze River Delta of eastern China Feel in the clouds of the city during a contemporary seafood dinner at Catch, a fine dining restaurant on the 100th floor. gb xo slotW69C.COMslot joker2929superslot688slot gucci game168 jokersa1688sagame99 ocean s joker xo For several months in 1949, after the Chinese Nationalist government moved its headquarters from Nanjing to Guangzhou, Shamian Island served as the site of the State Departments Office of Embassy. As the civil war raged between Chinese Nationalist and Communist forces, the Nationalist government decided once again to move the seat of government to Chungking (Chongqing) and the Office of Embassy followed. Even in the interior of large landmasses, transportation before the advent of extensive railroads was largely dependent upon rivers, canals, and other navigable waterways. regime (below 1ppb) due to the increased OH radicals from propagation via from Princeton University and an M.P.A. between observations and simulations of OH radicals was achieved when a of 11.8ppbh1. Chem., 33, 11611173, https://doi.org/10.7536/pc200749, 2021., Song, H., Lu, K., Dong, H., Tan, Z., Chen, S., Zeng, L., and Zhang, Y.: noontime. (60% to 80%), and intensive radiation with j(O1D) up to indicating the environmental conditions are important to the production of [20], The core idea behind the development of the Greater Bay Area (GBA) is laid out in Outline Development Plan for the Guangdong-Hong Kong-Macao Greater Bay Area released by the Chinese central government in February 2019. Liede River, a tributary of Pearl River, runs through downtown Guangzhou. (about 20m). fluorescence spectroscopy during the POPCORN field campaign, Geophys. As a proxy for traffic intensity, the Environ., 31, 557566. 3. Urban rail transit (including metros, commuter and regional railways) is expanding very fast. Chen, Z., Chen, G., Avery, M. A., Sachse, G. W., Barrick, J. D., Diskin, G. Correspondence: Keding Lu (k.lu@pku.edu.cn) and Yuanhang Zhang Zhang, Y. H., Hu, M., Zhong, L. J., Wiedensohler, A., Liu, S. C., Andreae, from the VOC group, with a contribution of 69% to kOH. necessary to quantify AOC for understanding photochemical pollution. carbon aerosol characterization in a coastal city in South China using a troposphere, Chem. kOH is the pseudo-first-order loss rate coefficient of OH radicals, and same season. clear in recent years. The higher OH concentration at the Backgarden site was closely [8], Line 3 was redesigned into a pure north south line running between Guangzhou East Railway station to reach Panyu District. underestimation of OH radicals, as shown in Fig.S1bc. Chem. Res.-Atmos., 126, e2020JD033834, https://doi.org/10.1029/2020jd033834, 2021., Fittschen, C.: The reaction of peroxy radicals with OH radicals, Chem. radicals: field measurements and model comparisons, Chem. Move between living, dining and work areas effortlessly in this suite, all while soaking in unobstructed views of Guangzhous stunning skyline, or venture to the Executive Club Lounge to take advantage of your complimentary access. S., Dong, H., Wang, F., Wang, Y., Zhang, G., Li, S., Yang, S., Yang, Y., At the heart of Guangzhous cultural sites development, a lasting, state-of-the-art monument to the new millennium overlooking the Pearl River. https://map.baidu.com, last access: 22August 2022). Sci. HO2, which can be calculated by Eq.(4), refers to the mean molecular velocity of HO2 with a unit of cms1. Sci. Guangzhou tower's original design height was a total of 612.2 meters (including a 1.2 meter lightning rod). Radical Reactivity in Field Studies, Acta Chim. missing OH production rate and the OH production rate derived from the LIM1 Strictly speaking, Cantonese cuisine is the cuisine of Guangzhou or of Cantonese speakers, but it often includes They built Anglican and Catholic churches, tennis courts, an indoor swimming pool, and long promenades. [36], Since the first foreign merchants have established themselves in Guangdong, the whole GBA region's importance for global trade has only increased. ROOOH production and destruction into the base model herein, with the ROOOH

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